Bottomley will take over the new responsibility with immediate effect and follows the departure of previous private banking head Richard Dunn, who quit at the end of 2011 to join Metro Bank.
Bottomley has over 25 years of experience in the private banking and wealth management sector.
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Most recently she was with Coutts, as the senior manager/client partner in the international private banking division.
The bank is expected to make further senior appointments in the coming weeks.
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